Thursday, January 6, 2011

Formulas and Names of Acids and Bases

     Most cleaning solutions are acids and bases and there is usually a right cleaning solution for a particular stain. Reading the label of the solution will give you an idea which product is the best for the stain that you will remove. Therefore, we must be familiar with the formulas of acids and bases and their respective names.
Naming Acids
     Acids like hydrogen chloride which are composed of only two elements, hydrogen, and a nonmetal, are called binary acids. The name hydrogen chloride refers to the pure compound which is a gas. When hydrogen chloride is dissolved in water, the solution formed hydrochloric acid. Other examples are the following:
               
Pure Acid
Aqueous Solution
HF(g)—hydrogen fluoride
HF(aq)—hydrofluoric acid
HI(g)—hydrogen iodide
HI(aq)—hydroiodic acid
 
Many other acids, called ternary acids, consist of three elements—hydrogen and two other nonmetals. Many of these acids are oxyacids, that is, one of the two nonmetals is oxygen. Examples are nitric acid and sulfurous acid.
The names of these oxyacids are based on the number of oxygen atoms per molecule.
Naming Oxyacids of Sulfur
Formula
Name
Formula and Name of Oxyanion Formed upon Reaction with Water
H2SO3
Sulfurous acid
SO3-2, sulfite
H2SO4
Sulfuric acid
SO4-2, sulfate

      Take note of the progression of the change in the names of the acids in each set as related to the progression in the number of oxygen atoms per molecule of the acid.
Naming Oxyacids of Chlorine
Scheme for Naming the Acids
Formula
Name
Formula and Name of Oxyanion Formed upon Reaction with Water
Hypo___ous 
HClO
Hypochlorous acid
ClO-, hypochlorite
___ous
HClO2
Chlorous acid
ClO2-, chlorite
___ic
HClO3
Chloric acid
ClO3-, chlorate
Per___ic
HClO4
Perchloric acid
ClO4-, perchlorate

Common Acids and Their Uses
Name
Uses
Acetic acid
Acid in vinegar used to season and preserve food; cleans and deodorizes
Hydrochloric acid
Aids in digestion; used as toilet bowl cleaner and for cleaning metal surfaces
Sulfuric acid
Used in automobile batteries and in making dyes and plastics; a dehydrating agent
Nitric acid
Used in making explosives and fertilizers
Phosphoric acid
Removes hard water deposits; used in making fertilizers; used in softdrinks (in dilute form)
Carbonic acid
Used in the manufacture of carbonated drinks
Acetylsalicylic acid (aspirin)
Reduces pain and inflammation

Naming Bases
     Bases are compounds consisting of a metal and a hydroxide ion. They dissociate into these ions when dissolved in water. Examples of base dissociation reactions are:
                NaOH       H2O       Na+(aq) + OH-(aq)
                        Ca(OH)2(s)       H2O        Ca2+(aq) + 2 OH-(aq)
     Bases are named just like binary acids in pure form; the ions are named, then combined.
                Example 1: NaOH
                Ions: Na+- sodium
                      OH- - hydroxide
                Base: sodium hydroxide
                Example 2: NH4OH
                Ions: NH4+- ammonium
                      OH- - hydroxide
                Base: ammonium hydroxide
Common Bases and Their Uses
Name
Uses
Sodium hydroxide
Used in making soaps and detergents; a drain and oven cleaner
Lithium hydroxide
Used in removing CO2 from air in confined areas such as submarines and spaceships
Magnesium hydroxide (in Milk of Magnesia)
Used as an antacid in small dosages and laxative in large amounts
Aluminum hydroxide
Used as an antacid with no dosage restrictions
Ammonia
Used in the production of fertilizers and cleaning solutions; revives patients who fainted


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