Thursday, January 6, 2011

The pH Concept

Changes in the acidity or basicity of some solutions can be critical in some systems such as the following:
  • a body of water supporting aquatic plants and animals
  • our stomachs digesting ingested food
  • cells of living organisms where vital life processes are carried out
  • some industrial processes where reactions take place at a desired rate
As discussed earlier, the acidity of a solution is measured by the hydronium ion concentration. For most solutions this is a very small number, usually expressed using exponential notation. In 1909, Soren Sorensen, a Danish biochemist, proposed the pH scale as a more convenient way of expressing hydronium ion concentration. The symbol pH stands for some German words which literally mean ' the power of the hydrogen ion.'

The pH of a solution is defined as the negative of the logarithm of the hydronium ion concentration.

pH = -log [H3O+]
Pure water has a hydronium ion concentration of 1 x 10 raised to -7. Thus, using the formula given above, we can now say that pure water has a pH of 7.

 
pH Box
pH of Common Substances
  • 1.0 M HCl-pH 0
  • Battery acid-pH 1
  • Gastric juice-pH 1.6-1.8
  • Calamansi juice-pH 2.2
  • Vinegar-pH 2.8
  • Apple juice-pH 3
  • Carbonated drink-pH 3.1
  • Orange juice-pH 3.5
  • Tomato juice-pH 4.2
  • Urine-pH 6.1
  • Milk-pH 6.5
  • Saliva-pH 6.5
  • Pure water-pH 7
  • Blood-pH 7.4
  • Seawater-pH 8.4
  • Milk of Magnesia-pH 10.5
  • 1.0 M NaOH-pH 14
 

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